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Publication --> 2017

"Catalytic enantioselective addition of diethyl phosphite to N-thiophosphinoyl ketimines: preparation of (R)-diethyl(1-amino-1-phenylethyl)phosphonate"
Lin, S.; Otsuka, Y.; Yin, L.; Kumagai, N.; Shibasaki, M.
Org. Synth. 2017, 94, 313.


Catalytic Asymmetric Total Synthesis and Stereochemical Revision of Leucinostatin A: A Modulator of Tumor-Stroma Interaction
Abe, H.; Ouchi, H.; Sakashita, C.; Kawada, M.; Watanabe, T.; Shibasaki, M.
Chem. Eur. J. 2017, 23, 11792.


Direct Catalytic Asymmetric Aldol Addition of an ƒ¿-CF3 Amide to Arylglyoxal Hydrates
Matsuzawa, A.; Noda, H.; Kumagai, N.; Shibasaki, M.
J. Org. Chem. 2017, 82, 8304.


Photocatalytic ƒ¿-Acylation of Ethers
Sun, Z.; Kumagai, N; Shibasaki, M.
Org. Lett. 2017, 19, 3727.



"Direct N-acylation of sulfoximines with carboxylic acids catalyzed by the B3NO2 heterocycle"
Noda, H.; Asada, Y.; Shibasaki, M.; Kumagai, N.
Chem. Commun. 2017, 53, 7447.



"ƒ¿,ƒÀ-Unsaturated Amides as Dipolarophiles: Catalytic Asymmetric exo-Selective 1,3-Dipolar Cycloaddition with Nitrones"
Zhang, M.; Kumagai, N.; Shibasaki, M.
Chem. Eur. J. 2017, 23, 12450. Selected as Cover Picture and Cover Profile.


"ƒ¿-Halo Amides as Competent Latent Enolates: Direct Catalytic Asymmetric Mannich-Type Reaction"
Sun, B.; Balaji, P. V.; Kumagai, N.; Shibasaki, M.
J. Am. Chem. Soc. 2017, 139, 8295.


"Leptolyngbyolides, Cytotoxic Macrolides from the Marine Cyanobacterium Leptolyngbya sp.: Isolation, Biological Activity, and Catalytic Asymmetric Total Synthesis"
Cui, J.; Morita, M.; Ohno, O.; Kimura, T.; Teruya, T.; Watanabe, T.; Suenaga, K.; Shibasaki, M.
Chem. Eur. J. 2017, 23, 8500.


"Cu/Pd Synergistic Dual Catalysis: Asymmetric ƒ¿-Allylation of an ƒ¿-CF3 Amide"
Saito, A.; Kumagai, N.; Shibasaki, M.
Angew. Chem. Int. Ed. 2017, 56, 5551. Highlighted in Synfacts 2017, 13, 715.


"Catalytic asymmetric synthesis of CF3-substituted tertiary propargylic alcohols via direct aldol reaction of ƒ¿-N3 amide"
Noda, H.; Amemiya, F.; Weidner, K.; Kumagai, N.; Shibasaki, M.
Chem. Sci. 2017, 8, 3260.


"Reversible Stereoselective Folding/Unfolding Fueled by the Interplay of Photoisomerism and Hydrogen Bonding"
Opie, C. R.; Kumagai, N.; Shibasaki, M.
Angew. Chem. Int. Ed. 2017, 56, 3349.


"Unique Physicochemical and Catalytic Properties Dictated by the B3NO2 Ring System"
Noda, H.; Furutachi, M.; Asada, Y.; Shibasaki, M.; Kumagai, N.
Nature Chem. 2017, 9, 571. Highlighted in C&EN (January 30, 2017); –ˆ“úV•·i2017”N1ŒŽ31“új; “úŒoŽY‹ÆV•·i2017”N1ŒŽ31“új; Synform 2017, 10, A165.


"Asymmetric flow catalysis: Mix-and-go solid-phase Nd/Na catalyst for expeditious enantioselective access to a key intermediate of AZD7594"
Nonoyama, A.; Kumagai, N.; Shibasaki, M.
Tetrahedron 2017, 73, 1517. Highlighted in Synfacts 2017, 13,462; Synfacts 2017, 13, 559.


"Direct Catalytic Asymmetric Aldol Reaction of ƒ¿-Alkylamides"
Liu, Z.; Takeuchi, T.; Pluta, R.; Arteaga, F. A.; Kumagai, N.; Shibasaki, M.
Org. Lett. 2017, 19, 710.


"Catalytic Asymmetric Synthesis of 2,3,3,3-Tetrafluoro-2-Methyl-1-Arylpropan-1-Amines as Useful Building Blocks for SAR-Studies"
Brewitz, L.; Kumagai, N.; Shibasaki, M.
J. Fluor. Chem. 2017, 194, 1.



"Pyramidalization/Twisting of the Amide Functional Group via Remote Steric Congestion Triggered by Metal Coordination"
Adachi, S.; Kumagai, N.; Shibasaki, M.
Chem. Sci. 2017, 8, 85. Selected as inside front cover


"Strategic Immobilization of Molecular Catalysts onto Carbon Nanotubes via Noncovalent Interaction for Catalytic Organic Transformations"
Kumagai, N.; Shibasaki, M.
Isr. J. Chem. 2017, 57, 270.


"Catalytic Asymmetric Synthesis of the C1-C15 Segment of Spirastrellolide A"
Sahara, Y.; Cui, J.; Furutachi, M.; Chen, J.; Watanabe, T.; Shibasaki, M.
Synthesis 2017, 49, 69.