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Publication --> 2010

"A Heterobimetallic Ni/La-salan Complex for Catalytic Asymmetric Decarboxylative 1,4-Addition of Malonic Acid Half-Thioester"
Furutachi, M.; Mouri, S.; Matsunaga, S.; Shibasaki, M.
Chem. Asian J. 2010, 5, 2351.


"Copper(I)-Secondary Diamine Complex-Catalyzed Enantioselective Conjugate Boration of Linear ,-Disubstituted Enones"
Chen, I-H.; Kanai, M.; Shibasaki, M.
Org. Lett. 2010, 12, 4098.


"Catalytic Asymmetric Aza-Morita-Baylis-Hillman Reaction of Methyl Acrylate: Role of a Bifunctional La(O-iPr)3/Linked-BINOL Complex"
Yukawa, T.; Seelig, B.; Xu, Y.; Morimoto, H.; Matsunaga, S.; Berkessel, A.; Shibasaki, M.
J. Am. Chem. Soc. 2010, 132, 11988.


"Direct Catalytic Asymmetric Conjugate Addition of Terminal Alkynes to ,-Unsaturated Thioamides"
Yazaki, R.; Kumagai, N.; Shibasaki, M.
J. Am. Chem. Soc. 2010, 132, 10275.


"Direct Catalytic Asymmetric Aldol Reaction of Thioamides: a Concise Asymmetric Synthesis of (R)-Fluoxetine"
Iwata, M.; Yazaki, R.; Kumagai, N.; Shibasaki, M.
Tetrahedron: Asymmetry 2010, 21, 1688.


"syn-Selective Catalytic Asymmetric 1,4-Addition of -Ketoanilides to Nitroalkenes under Dinuclear Nickel Catalysis"
Xu, Y.; Matsunaga, S.; Shibasaki, M.
Org. Lett. 2010, 12, 3246.


"Catalytic Enantioselective Construction of -Quaternary Carbons via a Conjugate Addition of Cyanide to ,-Disubstituted ,-Unsaturated Carbonyl Compounds"
Tanaka, Y.; Kanai, M.; Shibasaki, M.
J. Am. Chem. Soc. 2010, 132, 8862.


"Design and Synthesis of Resin-Conjugated Tamiflu Analogs for Affinity Chromatography"
Kimura, Y.; Yamatsugu, K.; Kanai, M.; Echigo, N.; Kuzuhara, T.; Shibasaki, M.
Bull. Korean Chem. Soc. 2010,31, 588.


"The First Catalytic Asymmetric Total Synthesis of ent-Hyperforin"
Shimizu, Y.; Shi, S.-L.; Usuda, H.; Kanai, M.; Shibasaki, M.
Tetrahedron 2010, 66, 6569.


"Catalytic Asymmetric Synthesis of R207910"
Saga, Y.; Motoki, R.; Makino, S.; Shimizu, Y.; Kanai, M.; Shibasaki, M.
J. Am. Chem. Soc. 2010, 132, 7965.


"Identification of Modular Chiral Bisphosphines Effective for Cu(I)-Catalyzed Asymmetric Allylation and Propargylation of Ketones"
Shi, S.-L.; Xu, L.-W.; Oisaki, K.; Kanai, M.; Shibasaki, M.
J. Am. Chem. Soc. 2010, 132, 6638.


(Inside cover picture)

"Solvent-dependent Self-discrimination of Bis(2-hydroxyphenyl)diamides"
Matsuzawa, A.; Nojiri, A.; Kumagai, N.; Shibasaki, M.
Chem. Eur. J. 2010, 16, 5036.


"Direct Catalytic Asymmetric Addition of Allyl Cyanide to Ketones via Soft-Lewis Acid/Hard Bronsted Base/Hard Lewis Base Cooperative Catalysis"
Yazaki, R.; Kumagai, N.; Shibasaki, M.
J. Am. Chem. Soc. 2010, 132, 5522.


"Catalytic Asymmetric Nitro-Mannich Reactions with a Yb/K Heterobimetallic Catalyst"
Nitabaru, T.; Kumagai, N.; Shibasaki, M.
Molecules 2010, 15, 1280.


"Heterobimetallic Transition Metal/Rare Earth Metal Bifunctional Catalysis: A Cu/Sm/Schiff Base Complex for Syn-Selective Catalytic Asymmetric Nitro-Mannich Reaction"
Handa, S; Gnanadesikan, V.; Matsunaga, S.; Shibasaki, M.
J. Am. Chem. Soc. 2010, 132, 4925.


"Catalytic Asymmetric Conjugate Addition of -Cyanoketones for the Construction of a Quaternary Stereogenic Center"
Kawato, Y.; Takahashi, N.; Kumagai, N.; Shibasaki, M.
Org. Lett. 2010, 12, 1484.


"Direct Catalytic Asymmetric Vinylogous Mannich-Type and Michael Reactions of an ,-Unsaturated -Butyrolactam under Dinuclear Nickel Catalysis"
Shepherd, N. E.; Tanabe, H.; Xu, Y.; Matsunaga, S.; Shibasaki, M.
J. Am. Chem. Soc. 2010, 132, 3666.


"Catalytic Asymmetric 1,4-Additions of -Keto Esters to Nitroalkenes Promoted by a Bifunctional Homobimetallic Co2-Schiff Base Complex"
Furutachi, M.; Chen, Z.; Matsunaga, S.; Shibasaki, M.
Molecules 2010, 15, 532.


"Catalytic Asymmetric Total Synthesis of ent-Hyperforin"
Shimizu, Y.; Shi, S-L.; Usuda, H.; Kanai, M.; Shibasaki, M.
Angew. Chem. Int. Ed. 2010, 49, 1103.


"Catalytic Asymmetric Synthesis of 3-Aminooxindoles: Enantiofacial Selectivity Switch in Bimetallic vs Monometallic Schiff Base Catalysis"
Mouri, S.; Chen, Z.; Mitsunuma, H.; Furutachi, M.; Matsunaga, S.; Shibasaki, M.
J. Am. Chem. Soc. 2010, 132, 1255.