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Publication --> 2019

"Solvent-Dependent Enantiodivergence in anti-Selective Catalytic Asymmetric Nitroaldol Reactions"
Karasawa, T.; Saito, A.; Kumagai, N.; Shibasaki, M.
Org. Lett. 2019, 21, 3581.



"All Non‐Carbon B3NO2 Exotic Heterocycles: Synthesis, Dynamics, and Catalysis"
Opie, C. R.; Noda, H.; Shibasaki, M.; Kumagai, N.
Chem. Eur. J. 2019, 25, 4648. Selected as Inside Front Cover.
Pym-DATB Catayst is commercially available from SIGMA-ALDRICH.



"A C4N4 Diaminopyrimidine Fluorophore"
Noda, H.; Asada, Y.; Maruyama, T.; Takizawa, N.; Noda, N. N.; Shibasaki, M.; Kumagai, N.
Chem. Eur. J. 2019, 25, 4299. Selected as Cover Picture (Cover Profile).


"Catalytic Asymmetric Synthesis of syn Aldols with Methyl Ketone Functionality and anti Aldols with a Thioamide Group"
Ota, Y.; Li, Z.; Kumagai, N.; Shibasaki, M.
Synlett 2019, 30, 620.


"Direct Catalytic Asymmetric Aldol Reaction of α‐Alkoxyamides to α‐Fluorinated Ketones"
Pluta, R.; Kumagai, N.; Shibasaki, M.
Angew. Chem. Int. Ed. 2019, 58, 2459.



"Neighboring Protonation Unveils Lewis Acidity in the B3NO2 Heterocycle"
Noda, H.; Asada, Y.; Shibasaki, M.; Kumagai, N.
J. Am. Chem. Soc. 2019, 141, 1546.


"Direct Catalytic Asymmetric Mannich-Type Reaction of an α-CF3 Amide to Isatin Imines"
Yu, J.-S.; Noda, H.; Kumagai, N.; Shibasaki, M.
Synlett 2019, 30, 488.


"A fluorogenic C4N4 probe for azide-based labelling"
Noda, H.; Asada, Y.; Shibasaki, M.; Kumagai, N.
Org. Biomol. Chem. 2019, 17, 1813.


"7-Azaindoline Auxiliary: A Versatile Attachment Facilitating Enantioselective C-C Bond-Forming Catalysis"
Kumagai, N.; Shibasaki, M.
Synthesis 2019, 51, 185.



"Achiral Trisubstituted Thioureas as Secondary Ligands to Cu(I) Catalysts: Direct Catalytic Asymmetric Addition of α‐Fluoronitriles to Imines"
Balaji, P. V.; Brewitz, L.; Kumagai, N.; Shibasaki, M.
Angew. Chem. Int. Ed. 2018, 58, 2644. Selected as inside back cover.