News
Feb. 2, 2018
Dr. Naoya Kumagai won MBLA 2017.
Dec. 14, 2017Dr. Takumi Watanabe won The Pharmaceutical Society of Japan Award for Divisional Scientific Promotion '18.
Dec. 11, 2017Our dioxaazatriborinane (B3NO2) was nominated for "Molecules of the year (C&EN)".
Feb. 1, 2017Our recent research results on the novel catalyst for amidation were described in C&EN (Jan. 30th, 2017) , Mainichi Shimbun (Jan. 31st, 2017), and Nikkei Sangyo Shimbun (Jan. 31st, 2017).
Jun. 1, 2015Our lab moved to the new building.
TOP
Recent publication
"Skeletal Modification of Phenols into Benzo-Fused Seven-Membered N,O-Heterocycles via Catalytic Alkyl Nitrene C(sp2)—H Amination"
Singh, P. R.; Asada, Y.; Noda, H.; Shibasaki, M.
Org. Lett. 2026, ASAP.
"Catalytic Asymmetric Benzoin Condensation for the Synthesis of Natural Products and Their Analogs"
Abe, H.; Sasaki, K.; Sakashita, C.; Watanabe, S.; Noda, H.; Watanabe, T.; Shibasaki, M.
Org. Lett. 2025, 27, 13702.
"Direct Catalytic Asymmetric Conjugate Addition of Benzofuran-3(2H)-Ones to α,β-Unsaturated Thioamides: Stereodivergent Synthesis of Rocaglaol"
Samanta, S.; Noda, H.; Watanabe, T.; Cui, J.; Shibasaki, M.
Angew. Chem. Int. Ed. 2024, 64, e202415805.
"Copper-Catalyzed Direct Asymmetric Aldol Reaction of Glycine Schiff Bases to Access syn-β-Hydroxy-α-amino Esters"
Takeuchi, T.; Shibasaki, M.
Org. Lett. 2024, 26, 7981.
"Catalytic Asymmetric Mannich-Type Reaction of α-Haloacetonitriles"
Saito, A.; Shibasaki, M.
Org. Lett. 2024, 26, 7546.
"Synthesis of Heteroaromatic-Fused Cyclic β-Amino Acids by Rhodium-Catalyzed Electrophilic Amination"
Manoharan, R.; Asada, Y.; Noda, H.; Shibasaki, M.
Synthesis 2024, 56, 1563.
"Direct Catalytic Enantioselective Conjugate Addition of α-Substituted Benzyl Nitriles to Alkyl Acrylates"
Samanta, S.; Cui, J.; Otsuka, Y.; Watanabe, T.; Shibasaki, M.
Org. Lett. 2024, 26, 2255.
"anti-Selective Synthesis of Substituted β-Homoprolines by Rhodium Alkyl Nitrene C–H Insertion"
Tang, X.; Noda, H.; Shibasaki, M.
Synlett 2023, eFirst.
"Examining the effects of additives and precursors on the reactivity of rhodium alkyl nitrenes generated from substituted hydroxylamines"
Noda, H.; Asada, Y.; Shibasaki, M.
Front. Chem. 2023, 11, 1271896.
"Catalytic Asymmetric Vinylogous Conjugate Addition of Butenolide to 2-Ester-Substituted Chromones: Access to Chiral Chromanone Lactones via Trapping of a Copper(I) Enolate by Trimethyl Borate"
Cui, J.; Oriez, R.; Samanta, S.; Noda, H.; Watanabe, T.; Shibasaki, M.
Org. Lett. 2023, 25, 8367.
"Locking the Conformation of a Paddlewheel Rhodium Complex: Design, Synthesis, and Applications in Catalytic Nitrene Transfers"
Tang, X.; Noda, H.; Shibasaki, M.
Angew. Chem. Int. Ed. 2023, 63, e202311027.
"Brønsted Base-Catalyzed Direct 1,6-Conjugate Addition of Butenolide to p-Quinone Methides"
Cui, J.; Samanta, S.; Watanabe, T.; Shibasaki, M.
Asian J. Org. Chem. 2023, 12, e202300176.
"Less Is More: N(BOH)2 Configuration Exhibits Higher Reactivity than the B3NO2 Heterocycle in Catalytic Dehydrative Amide Formation"
Opie, C. R.; Noda, H.; Shibasaki, M.; Kumagai, N.
Org. Lett. 2023, ASAP.
"Asymmetric Syn-Selective Vinylogous Addition of Butenolides to Chromones via Al-Li-BINOL Catalysis"
Samanta, S.; Cui, J.; Noda, H.; Watanabe, T.; Shibasaki, M.
J. Org. Chem. 2023, 88, 1177.